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・ Nitrophila mohavensis
・ Nitrophila occidentalis
・ Nitrophorin
・ Nitrophosphate process
・ Nitric-oxide synthase (NAD(P)H-dependent)
・ Nitrica
・ Nitride
・ Nitriding
・ Nitridoborate
・ Nitrification
・ Nitrifying bacteria
・ Nitrilase
・ Nitrile
・ Nitrile anion
・ Nitrile hydratase
Nitrile reduction
・ Nitrile rubber
・ Nitrile ylide
・ Nitrilimine
・ Nitriliruptoridae
・ Nitrilium
・ Nitrilotriacetate monooxygenase
・ Nitrilotriacetic acid
・ Nitrite
・ Nitrite dismutase
・ Nitrite oxidoreductase
・ Nitrite reductase
・ Nitrite reductase (NAD(P)H)
・ Nitrite reductase (NO-forming)
・ Nitrite test


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Nitrile reduction : ウィキペディア英語版
Nitrile reduction
In nitrile reduction a nitrile is reduced to either an amine or an aldehyde with a suitable chemical reagent.
==Hydrogenation==
The largest scale application of nitrile reduction is their hydrogenation. Under idealized conditions, the reaction can afford either the primary amine
:
Depending on conditions, the intermediate imine can undergo attack by amine products to afford secondary and tertiary amines. Such reactions proceed via the intermediacy of enamines.〔 J. Barrault, Y. Pouilloux "Catalytic Amination Reactions Synthesis of fatty amines. Selectivity control in presence of multifunctional catalysts" Catalysis Today 1997 Volume Pages 137–153. 〕 Commercial applications of this technology is in the production of fatty amines and precursors to nylon.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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